Compared to the TePP and you will pentaphenylpyrrole (PPP), both TPM and you can TPM-Cl displayed prolonged emission wavelengths. Due to the equivalent chemical substances structures, that isn’t plausible to help you trait the significant Stokes shift to variations in the ability pit between the low singlet thrilled state (S1) and you can soil county (S0). We hence propose that the fresh purple emission represents a low triplet happy county (T1), that’s less than S1. dos, in which the contours are the same on the steady-condition emission spectra, discussing the new enough time existence functions from one another TPM and you will TPM-Cl. The brand new lifetimes of your TPM and you may TPM-Cl crystalline powders is 20.1 and you will 8.9 μs, respectively (Fig. S3 and you will Table S1).

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Chongqing Wulong Karst Part, Wulong Karst Land

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